@article{,
    author = {Chen, Xin; Bartlam, Cian; Lloret, Vicent; Badlyan, Narine Moses; Wolff, Stefan; Gillen, Roland; Stimpel-Lindner, Tanja; Maultzsch, Janina; Düsberg, Georg; Knirsch, Kathrin; Hirsch, Andreas},
    title = {Covalent Bisfunctionalization of Two-Dimensional Molybdenum Disulfide},
    editor = {},
    booktitle = {},
    series = {},
    journal = {Angewandte Chemie},
    address = {},
    publisher = {},
    edition = {},
    year = {2021},
    isbn = {},
    volume = {60},
    number =  {24},
    pages = {13484-13492},
    url = {https://doi.org/10.1002/anie.202103353},
    doi = {10.1002/anie.202103353},
    keywords = {covalent functionalization ; hybrid structures ; MoS2 ; nanosheets ; reactivity},
    abstract = {Covalent functionalization of two-dimensional molybdenum disulfide (2D MoS<sub>2</sub>) holds great promise in developing robust organic-MoS<sub>2</sub> hybrid structures. Herein, for the
first time, we demonstrate an approach to building up
a bisfunctionalized MoS<sub>2</sub> hybrid structure through successively
reacting activated MoS<sub>2</sub> with alkyl iodide and aryl diazonium
salts. This approach can be utilized to modify both colloidal
and substrate supported MoS<sub>2</sub> nanosheets. We have discovered
that compared to the adducts formed through the reactions of
MoS<sub>2</sub> with diazonium salts, those formed through the reactions
of MoS<sub>2</sub> with alkyl iodides display higher reactivity towards
further reactions with electrophiles. We are convinced that our
systematic study on the formation and reactivity of covalently
functionalized MoS<sub>2</sub> hybrids will provide some practical
guidance on multi-angle tailoring of the properties of 2D
MoS<sub>2</sub>
for various potential applications.
},
    note = {},
    institution = {Universität der Bundeswehr München, Fakultät für Elektrotechnik und Informationstechnik, EIT 2 - Institut für Physik, Professur: Düsberg, Georg},
    
    
}